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ChemistryDifficulty 2-4

Periodic Table

The periodic table lists every known element in order of atomic number, in 7 rows (periods) and 18 columns (groups). Elements in the same group have similar outer-electron arrangements and so behave in similar ways, which lets chemists predict properties from position. Mendeleev's 1869 version was so successful that it predicted elements nobody had yet found; the seventh period was completed in 2015.

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From atomic weight to atomic number

Mendeleev's ordering by atomic weight forced a few swaps, such as tellurium before iodine, justified by chemical similarity. Moseley's 1913 X-ray work, in which the square root of characteristic X-ray frequency plotted against atomic number gives a straight line, supplied a physical measurement of atomic number and resolved those inversions.

Predictive power

Mendeleev predicted about 68 for eka-aluminium's atomic weight; gallium, discovered in 1875, has 69.72. Scandium and germanium, also predicted, were found by 1886. The noble gases, discovered in the 1890s, slotted in as a new final group.

Common misconception: Periodicity is not a coincidence of tabulation: it reflects recurring outer-shell electron configurations, which is why electronegativity and typical ionic charge vary systematically with position.
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How the table is organised

Reading left to right along a row, the atomic number goes up by one each step. Rows are called periods and columns are called groups; IUPAC has recommended since 1988 that the groups simply be numbered 1 to 18. Some groups have family names: group 1 the alkali metals, group 2 the alkaline earth metals, group 17 the halogens and group 18 the noble gases.

  • Group (column): members typically have similar properties and similar outer-shell electron configurations.
  • Period (row): the atomic number rises by one from each element to the next.
  • Metals sit to the left and centre, non-metals to the upper right, with metalloids between them.

Worked example: reading a position

Chlorine has atomic number 17 and sits in group 17, period 3. Being in group 17 makes it a halogen, like fluorine above it in period 2, and halogens typically gain one electron to form 1− ions. Sodium, in group 1 of the same period, typically loses one electron to form a 1+ ion — which is why the two combine as Na⁺Cl⁻.

Trends you can read off the table

Electronegativity — how strongly an atom attracts the electrons in a bond — generally increases from left to right across a period and decreases down a group, so the most electronegative elements, led by fluorine, are at the upper right.

How we got here

In 1869, with about 60 elements known, Dmitri Mendeleev arranged them by increasing atomic weight and noticed that similar elements recurred at regular intervals. He left gaps and predicted the properties of missing elements; 'eka-aluminium' turned up as gallium in 1875. In 1913 Henry Moseley found a way to measure atomic number, which is why today's table is ordered by atomic number rather than atomic weight. In 2015 IUPAC verified elements 113, 115, 117 and 118, completing period 7, and named them in 2016.

Common misconception: A common belief is that the table is ordered by atomic mass. Mendeleev used atomic weight, but the modern table is ordered by atomic number; that is why tellurium (heavier) comes before iodine.
Info: The table's layout underpins chemical bonding: an element's group predicts the ions it tends to form and how strongly it attracts electrons.

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Content status: published 1 October 2026.

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